For a minute there I thought I had to get off my couch, when all the while the fact is we don't have to do anything much but keep things afloat for just a few decades more! In fact, we'd best shut up about PO, because if our offspring finds out we knew about it all along, they'll turn and wring our necks come 2036!
Joined: Apr 28, 2005 Posts: 3431 Location: West shore Lake Eire, MI, USA
Posted: Sun May 13, 2007 8:51 am Post subject: Re: Hydrogen GHG forcing increases?
Something nobody seems to want to talk about in the MSM is the risk the Hydrogen economy has for the environment. I am talking about the direct risk, not the lack of ene3rgy density, low EROEI or any of the other problems already explored either.
When hydrogen gas escapes into the atmosphere one of two things happen to it if it doesn't burn immediately. About 80% of the time it is absorbed into the soil where it is taken up by soil bacteria, which may or may not affect their life cycle. We don't know because nobody has published any detailed studies on this phenomenom yet. Because Hydrogen molecules only have 7% the density of atmoshperic gasses in general the other 20% of the time the hydrogen rises into the stratosphere before being absorbed. In these cases the hydrogen molecules react with OH radicals and O3 Ozone molecules to form water vapor. This lowers the abundance of OH radicals and Ozone in the stratosphere and as a side effect reduces their effectiveness at oxidizing Methane (CH4). This causes Methane to be more persistant in the atmosphere and as a GHG it is 20 to 23 times as effective at reflecting heat as CO2.
Before we go off the deep end with billions of dollars invested in this mythical hydrogen economy the Polliticians love to talk about shouldn't we study how spilled hydrogen is going to effect soil chemistry/biology and GHG persistance? Why do we always go haring off after the next great technobabble solution before we know if it will bite us in the behind through the law of unintended consequences?
Quote:
The pending change from a fossil fuel to a hydrogen-based economy has the potential to more than double the atmospheric abundance of molecular hydrogen (current tropospheric mixing ratio ~530 parts per billion by volume (ppbv)) because of difficulties containing hydrogen gas during production, transport, storage and use [1]. Potential effects on atmospheric chemistry include a decrease in the tropospheric abundance of gas phase hydroxyl radicals, which would result in an increased atmospheric lifetime for methane, and a decrease in stratospheric ozone [1, 2]. On the positive side, a widespread change to hydrogen fuel cell technology is predicted to decrease anthropogenic emissions of nitrogen oxide (NOx) and carbon monoxide by up to 50% [2].
Our understanding of the global H2 cycle is remarkably poor compared to that for other trace gases. The error associated with any particular source or sink term in the H2 budget ranges between +/-30 to +/-60% [3]. Soils are the dominant sink for atmospheric hydrogen, accounting for ~80% of the annual loss of H2 from the troposphere [4]. Removal of H2 by soils is generally referred to simply as 'surface deposition', reflecting the poorly understood nature of this biological process, which is thought to involve the enzymatic activity of soil hydrogenases [3]. Removal rates are known to vary with soil conditions, such as temperature and moisture, but well-defined relationships between deposition rates and these parameters have yet to be determined [5]. Moreover, little is known about the capacity of soil organisms to metabolise H2 at enhanced atmospheric levels, in particular, the details of consumption kinetics and enzyme saturation levels have yet to be investigated. The effects of soil disturbance by humans on H2 uptake rates are also poorly quantified (eg tillage, use of fertilizers, pesticides and herbicides).
This study will investigate uptake of H2 in a variety of natural and human-influenced soils, focusing on soil orders that are globally significant (Mollisols, Alfisols, Spodosols, Histosols, and Ultisols/Oxisols). Field sites will include sites in the United Kingdom, Canada, Scandinavia, and Cameroon. Experiments will include both in situ and laboratory investigations of H2 uptake rates and microbial kinetics, including the effects of soil moisture and temperature, and the application of common fertilizers, pesticides and herbicides on uptake characteristics. The student will receive training in gas chromatography and basic microbiology, including the use of an HgO/Hg reduction gas analyzer which is used to measure molecular hydrogen at ppbv levels.
BERKELEY – Discovery of the last piece of a long-standing puzzle - what happens to hydrogen gas in the atmosphere - will help scientists assess the impact of additional hydrogen escaping into the atmosphere if America moves to hydrogen-fueled vehicles.
In a study published in the Aug. 21 issue of Nature, a team of scientists from the University of California, Berkeley, the California Institute of Technology, the National Center for Atmospheric Research in Boulder, Colo., and UC Irvine finally balances the Earth's hydrogen budget, accounting for where the hydrogen comes from and where it goes.
"A balanced budget now means that we may be better able to predict what will happen if and when humans introduce and leak into the atmosphere vast quantities of hydrogen for fuel cells," said Kristie Boering, professor of chemistry and of earth and planetary science at UC Berkeley.
Until now, scientists thought they understood most sources and sinks of hydrogen - where it is produced and how it gets taken up in chemical reactions in the soil, the oceans and the atmosphere. But two distinct methods used to track the hydrogen provided significantly different results.
Scientists measuring hydrogen concentrations found that the major sink for hydrogen was in the soil - microbes metabolize the hydrogen gas (H2) for energy, thus removing hydrogen from the air, where it is one of the most abundant trace gases after methane.
Those tracing the course of hydrogen by looking at the relative amounts of two of its isotopes - standard hydrogen, whose nucleus consists of only one proton, and deuterium, which harbors an extra neutron in its nucleus - got a different answer. The data seemed to point to the major sink being reaction of hydrogen gas in the atmosphere with OH radicals, which "cleanse" the atmosphere of many reactive gases.
Her isotopic analysis showed that the extreme deuterium enrichment observed in stratospheric H2 must result not only from deuterium enrichment by the destruction of H2 when it reacts with OH, but also from deuterium enrichment in the series of chemical reactions occurring as methane (CH4) is oxidized to produce H2. In both instances, reactions involving deuterium proceed at a different rate than those involving hydrogen, leading to products with a deuterium/hydrogen ratio different from the ratio in the reacting chemicals.
LINK TWO _________________ Oxygen: - An intensely habit-forming accumulative toxic substance. As little
as one breath is known to produce a life-long addiction to the gas, which addiction invariably ends in death.--Isaac Asimov
Joined: Mar 04, 2005 Posts: 2567 Location: New Zealand
Posted: Wed May 16, 2007 12:03 am Post subject: Hydrogen cars can solve foreign oil problem
Hydrogen cars can solve foreign oil problem
Quote:
USA TODAY's article "Honda promises hydrogen sedan in '08" isn't just about another electric car. The hydrogen fuel-cell car is the ultimate answer to America's dependence on foreign oil, air pollution and global warming.
*Because hydrogen fuel can be made from water via electrolysis, all that is needed is plentiful electricity. The United States has enough nuclear fuel in the form of plutonium-239 and depleted uranium to supply all of our electrical power needs for the whole century using modern, safe nuclear power plants.
usatoday
Prof. Otto G. Raabe - Center for Health and the Environment; University of California, Davis, Calif. _________________ Human history becomes more and more a race between education and catastrophe. H. G. Wells.
Fatih Birol's motto: leave oil before it leaves us.
Posted: Wed May 16, 2007 1:08 am Post subject: Re: Hydrogen cars can solve foreign oil problem
you're gonna need a helluva lot of new nuclear power stations to be able to get the hydrogen. I think the estimate was for 64 new ones in the US alone just to run cars and trucks.
But they need to be up and running within, what a year or two?
Posted: Wed May 16, 2007 1:55 am Post subject: Re: Hydrogen cars can solve foreign oil problem
Why go through the hydrogen step when you can just use a highly efficien electric battery instead without all that insane loss of energy through electorlyzis, compression, leakage, cell-inefficiency.
The cycle where you first have electricity and then hydrogen and then convert it back to electricity will at least take away 50% of the energy .. currently I havent heard of any hydrogen-cycle wich has gotten to 50% efficiency yet. Granted combustion engines will have only about 20% efficiency in normal auto usage, so it could perhaps be more efficient than todays gasoline/diesel cars, but you should also compare it with todays electric cars wich are steadily improving the driving range and are of course far more efficient.
A battery easilly returns 95% of the electricity put in. Meaning that you would probably have to have twize as many nuclear power plants or solar power plants to power the same fleet of cars.
Posted: Wed May 16, 2007 4:20 am Post subject: Re: Hydrogen cars can solve foreign oil problem
purcatty : i see some anger in your two posts. I don't have the science to argue about your claims, but i've the feeling you are right :
Before knowing about peak oil back in 2004, i thought (just like everyone in the street) that we have 40 years of oil, and anyway that oil is not so necessary to our industrial civilization, as we have biofuels, nuclear, soon thermonuclear power, spacecrafts and artificial intelligence...
I thought that progress (or the thing called progress should i say)was some kind of invincible direction for mankind.
Now that i know about the ugly lie about oil and our dependance to it, i see newspapers, magazines, television and even people as the propaganda's tools of an agonizing system based on perpetual growth.
What makes me angry is not only that, it is most of all that even when things will get really bad (let's say in 2015), the liers will still have the power, and the poor people won't get the true reason for the lack of jobs/food/water/cars/planes/internet/medics/education
/electricity/ freedom.
Nota Bene : Fusion has nothing to do with plutonium, as it consists in fusionning 2 hydrogen atoms in 1 helium atom. Anyway, we are 50 years from thermonuclear energy. (Back in 1950, we were also 50 years from it (!)).
Let's generalize : We'll always 50 years from thermonuclear energy.
Posted: Wed May 16, 2007 6:07 am Post subject: Re: Hydrogen cars can solve foreign oil problem
KevO wrote:
you're gonna need a helluva lot of new nuclear power stations to be able to get the hydrogen. I think the estimate was for 64 new ones in the US alone just to run cars and trucks.
But they need to be up and running within, what a year or two?
I'm in. Let's do it gang!!! PO.com: solving the world's problems one step at a time.
Posted: Wed May 16, 2007 6:51 am Post subject: Re: Hydrogen cars can solve foreign oil problem
purcatty wrote:
Nothing. That is right, nothing at all, we're going to be without a lot of things and without our cars very soon.
Nothing can replace the ungodly amount of energy we waste every day.
Absolutely correct.
Unfortunately, the optimists want to present a different view. So the masses will continue as before, the overshoot and various distortions will extend to still greater extremes, and the upcoming crash will be horrific. Even worse than it would have been otherwise.
I suggest you stock up on ammunition. I am. _________________ Dieoff. Fun to watch. Better with hot buttered popcorn!
Posted: Wed May 16, 2007 6:54 am Post subject: Re: Hydrogen cars can solve foreign oil problem
Let's do these numbers another way:
Currently, there are 7.5 to 8 billion miles driven per day in the US alone.
Let us assume every car (including buses, semis, and SUVs) on the road today was a Tesla Roadster tomorrow. Chosen for it's mind-numbing efficiency. Theoretically around 220 W*h (at the plug) per mile. That's incredible. That's 18 miles per one load in an electric clothes dryer! Let's even take another conceit that fuel cells are 100% efficient users of hydrogen and there is no energy required to transport hydrogen, and no energy used in building the whole new infrastructure.
By that assumption, we need 1.7 TWh per day to drive the national traffic jam. That's not impossible. That's only about 18% of current electric use.
If the grid use were perfectly utilized and we were talking about 100% efficient battery electric cars, we would only need 71 GW of base installation, or 70 of the newest, largest nuclear reactor designs.
You'd have to double that number of GW installed to go to hydrogen iff the plants were high-temperature plants (pebble bed for instance) designed to reform hydrogen directly.
You'd have to easily triple the number if you were dealing with water-cooled steam-driven electric-reformer plants.
And keep building them, so growth can continue.
So, possible? Maybe, if that was the absolute priority of the nation, yes. Realistically, off by at least an order of magnitude. Every efficiency listed is best-case.
Joined: Nov 01, 2005 Posts: 796 Location: Euro high horse bastard on the run
Posted: Wed May 16, 2007 9:23 am Post subject: Re: Hydrogen cars can solve foreign oil problem
Lawnchair> Why Tesla Roadster, the lowlywood bimbo with 220Wh/mi from plug?
Btw. isn't it a BIT more in reality (heavy, bad aerodynamics)?
Try Loremo instead, 40Wh/km at wheels ~ 56Wh/km at plug =>91Wh/mi and for 1/6 of the cost..
I think the best fun now is to buy som solar arrays, electric car and off the grid home system. After PO you will be a TV personality for a week, and then dead meat as the new local warlord took interest in the latest hightech.. _________________ DOOMerotron: at all-time high [8.1] out of 10..
Posted: Wed May 16, 2007 11:46 am Post subject: Re: Hydrogen cars can solve foreign oil problem
Let's not forget, where are you going to get the people to crash-build all those nuke plants?
They don't exist.
See, the laws of supply and demand in a free market apply equally to the training of professional cadres. For the last 20-30 years the market has only been demanding enough for operation and maintenance of existing build, so that's what we have been getting. If you suddenly have the market demand enough to build and connect a new nuke plant every few months, you are going to have to wait another generation for them to go through school, university and training. You are not going to retrain existing personnel from other economic sectors. We have a high specialisation of labour these days, boasting a modern flexible workforce says nothing about your ability to fill those stubborn critical niches.
So even if you have the money, the willpower and the resources, you are not crash-building anything. There is no-one to do it! And there won't be for a period of time at least equal to the duration of the necessary education.
Forget the pipe dreams of what would happen if governments woke up tomorrow. Those opportunities always had a lead time.
Simmons' vague idea for a big project isn't going to work either, for the same reason, unless he thinks we have until after 2020 to start in earnest.
Everyone has a tendency to focus too much on the hardware and forget the people. If you plotted an age distribution of the energy industry as a whole, how would the bell curve be skewed? In the West I would guess heavily, with a median age of around 50, and signs of low recruitment during the 1980s and 90s (partly because of cutbacks/recession, partly because during this time business became far more sexy for the student applicant). Simmons has hinted at this forgotten aspect, but should really devote much more attention to it. The question of what a country is doing to train essential workers is every bit as important to its future as things.
With what people?
Unemployed machinists from the soon-to-be bankrupt automotive industry? They will be building power conversion equipment somewhere?
Show me the progress.
If a technology-based solution does not address how it will source, manage and retain the specialists required for implementation, I am not interested. Pushing the subject off the balance sheet into some future government experiment with technocracy is not going to cut it. The expected downslope of oil and gas depletion and ageing infrastructure and workforce dictate the timescale, we know it will be very quick on a human timescale, so your available human resource will not be much greater or much different than what it is today.
So again - hundreds of nuke plants, electrolysis plants, new power transmission and distribution system, hydrogen transportation and distribution system - who?
Posted: Wed May 16, 2007 2:01 pm Post subject: Re: Hydrogen cars can solve foreign oil problem
Twilight wrote:
So again - hundreds of nuke plants, electrolysis plants, new power transmission and distribution system, hydrogen transportation and distribution system - who?
That's one of the most cogent, insightful posts I've read in many a day. (For those who haven't read Twilight's post - every word of it, slowly and with full attention - please do so).
Let's say we want an Engineer with a MSc degree in an appropriate field of engineering. If we assume very bright, very hard working people who are well supported so they don't have to work their way through college, it will take about 7 years. That's 4 years for the BSc, and another 3 for the MSc. Maybe - just maybe - it could be trimmed down to 6 years (total) with an aggressive summer schedule.
Don't count on reducing that time by taking existing engineers and quickly switching them over.
Quote:
Without a steady infusion of new knowledge, the average engineering degree is obsolete in less than five years, and most engineers need to continue learning right up to the day when the boss hands them that gold watch.
So, even if The Powers That Be decided on a crash program this very moment, it would be about 4 years before the first newly minted, utterly green, completely inexperienced engineer came off the assembly line.
I have no doubt that similar numbers apply to skilled workers, from welders to machinists.
Oh, well. The optimists will probably point out that we have Asimo robots, therefore we can soon have all the robotic workers we need. Quick, everybody! Let's go shopping! _________________ Dieoff. Fun to watch. Better with hot buttered popcorn!
Posted: Wed May 16, 2007 2:49 pm Post subject: Re: Hydrogen cars can solve foreign oil problem
Indeed, had I been paying attention a decade ago, I would have gone into something energy-related (electric grid or nukee). The boom, bling, and reasonably easy world of the computer industry, especially in the last decade, has absolutely eaten away at the wetware pool that keeps the modern world operational, just as poor maintenance and hypertrophy has eaten away at the physical plant of modern society.
The number of years for a MSc is probably overrated. We don't need high-end engineering designers as badly as we need field engineers to replicate good standardized designs. An intense 1-2 year program (US Navy Nuke for a model) is probably appropriate, and a whole lot more salable to people who still paying student loans on their first careers' degrees. At least the very cream of the tech industry has the aptitude, and many would be retrained for the right incentives. This doesn't make things cheap at all, but really, it's that or collapse.
The other question is whether the West can brain-drain our way out of the engineering gap. It's what we've done with doctors (not that we actually need as many as we have) and IT (ditto). Power engineers are still largely native (50 year old plus "rednecks" seem the norm). Is life in the West enough better than elsewhere to suck talent out of the rest of the world?
Posted: Wed May 16, 2007 3:04 pm Post subject: Re: Hydrogen cars can solve foreign oil problem
lawnchair wrote:
Is life in the West enough better than elsewhere to suck talent out of the rest of the world?
Apparently. Look at the science and engineering faculty of most universities if you don't believe it.
How long that will last, given our fiscal policy, remains a question.
And whether those foreign countries will permit their top talent to keep coming here when they need them at home is another question, isn't it? _________________ Dieoff. Fun to watch. Better with hot buttered popcorn!
Joined: Apr 28, 2005 Posts: 3431 Location: West shore Lake Eire, MI, USA
Posted: Wed May 16, 2007 5:59 pm Post subject: Re: Hydrogen cars can solve foreign oil problem
I posted my big objection to the Hydrogen economy Sunday last but aparently nobody noticed it. Here dear colleges it is again, Hydrogen has untested but likely detrimental ecological impacts which are being ignored for pollitical reasons.
Something nobody seems to want to talk about in the MSM is the risk the Hydrogen economy has for the environment. I am talking about the direct risk, not the lack of ene3rgy density, low EROEI or any of the other problems already explored either.
When hydrogen gas escapes into the atmosphere one of two things happen to it if it doesn't burn immediately. About 80% of the time it is absorbed into the soil where it is taken up by soil bacteria, which may or may not affect their life cycle. We don't know because nobody has published any detailed studies on this phenomenom yet. Because Hydrogen molecules only have 7% the density of atmoshperic gasses in general the other 20% of the time the hydrogen rises into the stratosphere before being absorbed. In these cases the hydrogen molecules react with OH radicals and O3 Ozone molecules to form water vapor. This lowers the abundance of OH radicals and Ozone in the stratosphere and as a side effect reduces their effectiveness at oxidizing Methane (CH4). This causes Methane to be more persistant in the atmosphere and as a GHG it is 20 to 23 times as effective at reflecting heat as CO2.
Before we go off the deep end with billions of dollars invested in this mythical hydrogen economy the Polliticians love to talk about shouldn't we study how spilled hydrogen is going to effect soil chemistry/biology and GHG persistance? Why do we always go haring off after the next great technobabble solution before we know if it will bite us in the behind through the law of unintended consequences?
Quote:
The pending change from a fossil fuel to a hydrogen-based economy has the potential to more than double the atmospheric abundance of molecular hydrogen (current tropospheric mixing ratio ~530 parts per billion by volume (ppbv)) because of difficulties containing hydrogen gas during production, transport, storage and use [1]. Potential effects on atmospheric chemistry include a decrease in the tropospheric abundance of gas phase hydroxyl radicals, which would result in an increased atmospheric lifetime for methane, and a decrease in stratospheric ozone [1, 2]. On the positive side, a widespread change to hydrogen fuel cell technology is predicted to decrease anthropogenic emissions of nitrogen oxide (NOx) and carbon monoxide by up to 50% [2].
Our understanding of the global H2 cycle is remarkably poor compared to that for other trace gases. The error associated with any particular source or sink term in the H2 budget ranges between +/-30 to +/-60% [3]. Soils are the dominant sink for atmospheric hydrogen, accounting for ~80% of the annual loss of H2 from the troposphere [4]. Removal of H2 by soils is generally referred to simply as 'surface deposition', reflecting the poorly understood nature of this biological process, which is thought to involve the enzymatic activity of soil hydrogenases [3]. Removal rates are known to vary with soil conditions, such as temperature and moisture, but well-defined relationships between deposition rates and these parameters have yet to be determined [5]. Moreover, little is known about the capacity of soil organisms to metabolise H2 at enhanced atmospheric levels, in particular, the details of consumption kinetics and enzyme saturation levels have yet to be investigated. The effects of soil disturbance by humans on H2 uptake rates are also poorly quantified (eg tillage, use of fertilizers, pesticides and herbicides).
This study will investigate uptake of H2 in a variety of natural and human-influenced soils, focusing on soil orders that are globally significant (Mollisols, Alfisols, Spodosols, Histosols, and Ultisols/Oxisols). Field sites will include sites in the United Kingdom, Canada, Scandinavia, and Cameroon. Experiments will include both in situ and laboratory investigations of H2 uptake rates and microbial kinetics, including the effects of soil moisture and temperature, and the application of common fertilizers, pesticides and herbicides on uptake characteristics. The student will receive training in gas chromatography and basic microbiology, including the use of an HgO/Hg reduction gas analyzer which is used to measure molecular hydrogen at ppbv levels.
BERKELEY – Discovery of the last piece of a long-standing puzzle - what happens to hydrogen gas in the atmosphere - will help scientists assess the impact of additional hydrogen escaping into the atmosphere if America moves to hydrogen-fueled vehicles.
In a study published in the Aug. 21 issue of Nature, a team of scientists from the University of California, Berkeley, the California Institute of Technology, the National Center for Atmospheric Research in Boulder, Colo., and UC Irvine finally balances the Earth's hydrogen budget, accounting for where the hydrogen comes from and where it goes.
"A balanced budget now means that we may be better able to predict what will happen if and when humans introduce and leak into the atmosphere vast quantities of hydrogen for fuel cells," said Kristie Boering, professor of chemistry and of earth and planetary science at UC Berkeley.
Until now, scientists thought they understood most sources and sinks of hydrogen - where it is produced and how it gets taken up in chemical reactions in the soil, the oceans and the atmosphere. But two distinct methods used to track the hydrogen provided significantly different results.
Scientists measuring hydrogen concentrations found that the major sink for hydrogen was in the soil - microbes metabolize the hydrogen gas (H2) for energy, thus removing hydrogen from the air, where it is one of the most abundant trace gases after methane.
Those tracing the course of hydrogen by looking at the relative amounts of two of its isotopes - standard hydrogen, whose nucleus consists of only one proton, and deuterium, which harbors an extra neutron in its nucleus - got a different answer. The data seemed to point to the major sink being reaction of hydrogen gas in the atmosphere with OH radicals, which "cleanse" the atmosphere of many reactive gases.
Her isotopic analysis showed that the extreme deuterium enrichment observed in stratospheric H2 must result not only from deuterium enrichment by the destruction of H2 when it reacts with OH, but also from deuterium enrichment in the series of chemical reactions occurring as methane (CH4) is oxidized to produce H2. In both instances, reactions involving deuterium proceed at a different rate than those involving hydrogen, leading to products with a deuterium/hydrogen ratio different from the ratio in the reacting chemicals.
LINK TWO _________________ Oxygen: - An intensely habit-forming accumulative toxic substance. As little
as one breath is known to produce a life-long addiction to the gas, which addiction invariably ends in death.--Isaac Asimov
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